1. Right-click the desktop and choose New | Shortcut.
2. In the Create Shortcut dialog box, enter mailto: as the item to launch for the Outlook new mail message or the URL of the Google Docs document for which you need quick access. Click Next.
So the next time your boss asks you to email some report when you have closed Outlook while wrapping up for the day, fire up the Outlook New Mail message shortcut instead of opening Outlook explicitly.